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Devereux, Michael, Curran, Martin, McCann, Malachy, Casey, Michael T. and McKee, Vickie (1995) Synthesis and catalase activity of manganese (ii) complexes of cis-5-norbornene-endo-2, 3-dicarboxylic acid (ndaH2): x-ray crystal structure of [Mn(qb11-nda)(phen)2]• EtOH'H20 (phen = 1,10-phenanthroline). Polyhedron, 14 (15-16). pp. 2247-2253.
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Official URL: https://www.sciencedirect.com/journal/polyhedron
Abstract
Manganese(II) chloride reacts with the sodium salt of cis-5-norbornene-endo-
2,3-dicarboxylic acid (ndaH2) in aqueous media to give the manganese(II) complex [Mn
(nda)H20] (1). Complex 1 reacts with 1,10-phenanthroline (phen) to give the mononuclear
manganese(II) adduct [Mn(~/lql-nda)(phen)2] • EtOH" H20 (2). The X-ray crystal structure
of 2 shows the manganese atom at the centre of a distorted N402 octahedron comprising
four nitrogen atoms from two chelating phen ligands, and two oxygen atoms, one from
each of the two carboxylate functions of the nda 2- ligand. Spectroscopic and magnetic data
for 1 and 2 are reported, together with their catalytic activity towards the disproportionation
of H202.
| Item Type: | Article |
|---|---|
| Keywords: | Synthesis; catalase activity; manganese (ii) complexes; cis-5-norbornene-endo-2; 3-dicarboxylic acid (ndaH2); x-ray crystal structure; |
| Academic Unit: | Faculty of Science and Engineering > Chemistry |
| Item ID: | 9720 |
| Depositing User: | Dr. Malachy McCann |
| Date Deposited: | 26 Jul 2018 14:47 |
| Journal or Publication Title: | Polyhedron |
| Publisher: | Elsevier |
| Refereed: | Yes |
| URI: | https://mu.eprints-hosting.org/id/eprint/9720 |
| Use Licence: | This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available here |
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