McGinley, John, Creaven, Bernadette, Mahon, Mary and Moore, Ann-Marie (2006) Copper(11) complex of a tridentate N-Donor ligand with unexpected Cu-H interaction. Inorganic Chemistry Communications, 9. pp. 231-234.
PDF
ammoore_paper.pdf
Download (144kB)
ammoore_paper.pdf
Download (144kB)
Abstract
The new pyridineâamine ligand, meophdpa (bis(dipyridylmethyl)-4-methoxyaniline) was synthesised and reacted with copper(II) perchlorate. The X-ray crystal structure of the resulting complex revealed a monomeric copper(II) site, with the copper bound to the three ligand nitrogens in a relatively unusual meridional fashion, as well as a chloride and a water molecule. The sixth coordination site was, unexpectedly, occupied by a phenyl ring hydrogen atom.
Graphical abstract
A new pyridineâamine ligand has been prepared and its reaction with copper perchlorate characterised. An interesting phenyl-HâCu interaction was observed.
Item Type: | Article |
---|---|
Keywords: | Tridentate pyridineâamine ligand; Synthesis; Copper(II) complex; X-ray crystal structure; |
Academic Unit: | Faculty of Science and Engineering > Chemistry Faculty of Science and Engineering > Research Institutes > Institute of Immunology |
Item ID: | 924 |
Depositing User: | John McGinley |
Date Deposited: | 13 Mar 2008 |
Journal or Publication Title: | Inorganic Chemistry Communications |
Publisher: | Elsevier |
Refereed: | Yes |
Related URLs: | |
URI: | https://mu.eprints-hosting.org/id/eprint/924 |
Use Licence: | This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available here |
Repository Staff Only (login required)
Downloads
Downloads per month over past year