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Mahon, Mary F., McGinley, John, Rooney, A. Denise and Walsh, John M.D. (2009) Unusual copper(II) coordination mode from a potential Schiff-base reaction. Inorganica Chimica Acta, 362 (7). pp. 2353-2360. ISSN 0020-1693
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Abstract
The Schiff-base ligands (1–3) formed from the reaction of 3-hydroxybenzaldehyde with three alkyl diamines have been synthesised and characterised. They are stable both in solution and in the solid state for several weeks, with no degradation to the starting amines and aldehyde observed. The reactions of the three Schiff-base ligands with various MX2 salts (M = Cu, Ni or Zn; X = chloride, perchlorate or acetate) resulted in the cleavage of the imine bond and formation of metal–amine complexes, as well as the entrapment of a two coordinate CuCl2 molecule within the lattice in one particular case.
| Item Type: | Article |
|---|---|
| Keywords: | Schiff-base; Synthesis; X-ray structure; Transition metals; |
| Academic Unit: | Faculty of Science and Engineering > Chemistry |
| Item ID: | 7976 |
| Identification Number: | 10.1016/j.ica.2008.10.029 |
| Depositing User: | Dr. Denise Rooney |
| Date Deposited: | 01 Mar 2017 16:07 |
| Journal or Publication Title: | Inorganica Chimica Acta |
| Publisher: | Elsevier |
| Refereed: | Yes |
| Related URLs: | |
| URI: | https://mu.eprints-hosting.org/id/eprint/7976 |
| Use Licence: | This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available here |
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