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McMahon, Suzanne, Rochford, Jonathan, Halpin, Yvonne, Manton, Jennifer C., Harvey, Emma C., Greetham, Gregory M., Clark, Ian P., Rooney, A. Denise, Long, Conor and Pryce, Mary T. (2014) Controlled CO release using photochemical, thermal and electrochemical approaches from the amino carbene complex [(CO)5CrC(NC4H8)CH3]. Physical Chemistry Chemical Physics, 16. pp. 21230-21233. ISSN 1463-9076
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Abstract
Multimodal photo, thermal and electrochemical approaches toward
CO release from the amino carbene complex [(CO)5CrC(NC4H8)CH3]
is reported. Picosecond time resolved infrared spectroscopy was
used to probe the photo-induced early state dynamics leading to
CO release, and DFT calculations confirmed that CO release occurs
from a singlet excited state.
| Item Type: | Article |
|---|---|
| Keywords: | Controlled CO release; photochemical; thermal; electrochemical; approaches; amino carbene complex; [(CO)5CrC(NC4H8)CH3]; |
| Academic Unit: | Faculty of Science and Engineering > Chemistry |
| Item ID: | 7811 |
| Identification Number: | 10.1039/c4cp03758h |
| Depositing User: | Dr. Denise Rooney |
| Date Deposited: | 25 Jan 2017 15:03 |
| Journal or Publication Title: | Physical Chemistry Chemical Physics |
| Publisher: | Royal Society of Chemistry |
| Refereed: | Yes |
| Funders: | Irish Research Council, Science Foundation Ireland (SFI), Environmental Protection Agency (EPA) |
| Related URLs: | |
| URI: | https://mu.eprints-hosting.org/id/eprint/7811 |
| Use Licence: | This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available here |
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