Share and Export
Share and Export
Montagner, Diego and Longato, Bruno (2008) Synthesis and characterization of cis-[(PPh3)2Pt{9-MeAd(-H),N6N7}]X (X− = NO3, PF6): The first example of a platinum(II) complex containing the N6,N7-chelated 9-methyladenine anion. Inorganica Chimica Acta, 361 (6). pp. 1676-1680. ISSN 0020-1693
Preview
DM_synthesis.pdf
Download (236kB) | Preview
Abstract
Reaction between the binuclear hydroxo complex cis-[(PPh3)2Pt(μ-OH)]2X2 (X− = NO3, 1a; View the MathML sourcePF6-, 1b) and the model DNA base 9-methyladenine (9-MeAd) leads to the formation of the mononuclear species cis-[(PPh3)2Pt{9-MeAd(-H),N6N7}]X (X− = NO3, 2a; PF6, 2b), in which the nucleobase chelates the Pt(II) ion with the N6 and N7 atoms. The coordination mode of the nucleobase has been determinated through a multinuclear (1H, 31P, 13C, 15N and 195Pt) NMR analysis and the nuclearity of the complex has been obtained by E.S.I. mass spectrometry. 2 represents the first example of an isolated platinum complex in which the NH2-deprotonated adenine exhibits this binding mode.
| Item Type: | Article |
|---|---|
| Keywords: | Platinum(II) complexes; 9-Methyladenine; Multinuclear NMR; Phosphine; |
| Academic Unit: | Faculty of Science and Engineering > Chemistry |
| Item ID: | 7037 |
| Identification Number: | 10.1016/j.ica.2007.02.025 |
| Depositing User: | Diego Montagner |
| Date Deposited: | 21 Mar 2016 17:23 |
| Journal or Publication Title: | Inorganica Chimica Acta |
| Publisher: | Elsevier |
| Refereed: | Yes |
| Related URLs: | |
| URI: | https://mu.eprints-hosting.org/id/eprint/7037 |
| Use Licence: | This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available here |
Repository Staff Only (login required)
- Item control page
Downloads
Downloads per month over past year
