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Elmes, Robert B.P., Kitchen, Jonathan A., Williams, D. Clive and Gunnlaugsson, Thorfinnur (2012) Pushing the limit: synthesis, photophysical and DNA binding studies of a NIR-emitting Ru(II)-polypyridyl probe with ‘light switch’ behaviour. Dalton Transactions, 41 (22). pp. 6607-6610. ISSN 1477-9226
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Abstract
The new Ru(II) polypyridyl complex 1 was synthesised using
microwave irradiation from the new polypyridyl ligand 2
‘DipyTAP’, and its photophysical properties, and DNA
binding abilities were investigated using various spectroscopic
techniques; and 1 was shown to act as a ‘NIR molecular
light switch’ for DNA with an emission window between
680 and 860 nm.
| Item Type: | Article |
|---|---|
| Additional Information: | The definitive version of this article is available at Dalton Trans., 2012, 41, 6607 DOI: 10.1039/c2dt00020b . We thank Science Foundation Ireland (SFI PI Award 2010, and SFI RFP Awards 2008 and 2009), and The Irish Research Council for Science, Engineering & Technology (IRCSET) (Postdoctoral Fellowship to JAK, Postgraduate Fellowship to RBPE) for financial support, and Dr John E. O'Brian and Dr Martin Feeney for helping out with NMR and MS, respectively. |
| Keywords: | synthesis; photophysical; DNA binding studies; NIR-emitting Ru(II)-polypyridyl probe; ‘light switch’ behaviour; |
| Academic Unit: | Faculty of Science and Engineering > Chemistry |
| Item ID: | 5637 |
| Identification Number: | 10.1039/c2dt00020b |
| Depositing User: | Robert Elmes |
| Date Deposited: | 18 Dec 2014 17:31 |
| Journal or Publication Title: | Dalton Transactions |
| Publisher: | Royal Society of Chemistry |
| Refereed: | Yes |
| Funders: | Science Foundation Ireland, Irish Research Council for Science Engineering & Technology |
| Related URLs: | |
| URI: | https://mu.eprints-hosting.org/id/eprint/5637 |
| Use Licence: | This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available here |
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