Data extracted from Synthetic Aperture Radar (SAR) have been widely employed to estimate soil properties. However, these studies are typically constrained to bare soil conditions, as soil information retrieval in vegetated areas remains challenging. Polarimetric decomposition has emerged as a potentially useful method to separate the scattering contributions of different targets (e.g. canopy/leaves and the underlying soil), which is of significance for areas that are near-permanently covered in low-lying vegetation (e.g. grass) like Ireland – the study area for this investigation. Here, we test the surface scattering mechanism, derived from H-alpha dual-pol decomposition, together with other covariates, to estimate percentages of sand, silt, and clay, over vegetated terrain, using Sentinel 1 data (dual-pol C-band SAR). The statistical modelling approaches evaluated – linear regression (LRM) and tree-based regression models (machine learning) – explicitly consider the compositional nature of soil texture. When compared to the models fitted without surface scattering data, results showed that the inclusion of the surface scattering data improved estimates of silt and clay, with the compositional linear regression model, and estimates of sand and silt fractions with different tree-based models. While not without limitations, our study demonstrated that the polarimetric decomposition method, which is typically used for classification and segmentation purposes, could also be used for soil property estimation, broadening the application of this technique in microwave remote sensing studies.