Jemmeli, Dhouha, Dridi, Chérif, Abbas, Mohammed Nooredeen and Dempsey, Eithne (2021) Development of highly sensitive and selective bisphenol A sensor based on a cobalt phthalocyanine-modified carbon paste electrode: application in dairy analysis. Analytical Methods, 13 (39). pp. 4674-4682. ISSN 1759-9660
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Abstract
The development of an accurate, sensitive and selective sensor for the detection of bisphenol A (BPA) based
on the incorporation of a new phthalocyanine derivative, cobalt phthalocyanine, C,C,C,C-tetracarboxylic
acid-polyacrylamide (CoPc-PAA) into a carbon-paste matrix is presented using voltammetry and constant potential techniques. The influence of measuring parameters such as pH and scan rate on the analytical performance of the sensor was evaluated. Several kinetic parameters such as electron transfer number (n), charge transfer coefficient (a), electrode surface area (A) and diffusion coefficient (D) were also calculated. Under optimum conditions, particularly at pH 7.2, the BPA sensor resulted in a wide linear range from 25x10x11M to 2.5 x 10 x 7M and a limit of detection as low as 63.5 pM. Based on these findings, it can be
concluded that our sensor can be substantially utilized for detecting BPA in spiked milk samples
Item Type: | Article |
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Additional Information: | Cite as: Jemmeli, D., Dridi, C., Abbas, M.N. & Dempsey, E. 2021, "Development of highly sensitive and selective bisphenol A sensor based on a cobalt phthalocyanine-modified carbon paste electrode: application in dairy analysis", Analytical methods, vol. 13, no. 39, pp. 4674-4682. |
Keywords: | Bisphenol A; Carbon; Charge transfer; Cobalt; Diffusion coefficient; Electrodes; Electron transfer; Mathematical analysis; Milk; Parameters; pH; pH effects; Polyacrylamide; Sensors |
Academic Unit: | Faculty of Science and Engineering > Chemistry Faculty of Science and Engineering > Research Institutes > Human Health Institute |
Item ID: | 17382 |
Identification Number: | 10.1039/d1ay00827g |
Depositing User: | Eithne Dempsey |
Date Deposited: | 06 Jul 2023 10:39 |
Journal or Publication Title: | Analytical Methods |
Publisher: | Royal Society of Chemistry |
Refereed: | Yes |
Related URLs: | |
URI: | https://mu.eprints-hosting.org/id/eprint/17382 |
Use Licence: | This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available here |
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