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Devereux, Michael, Curran, Martin, McCann, Malachy, Casey, Michael T. and McKee, Vickie (1995) Synthesis and catalase activity of manganese(II) complexes of cis-5-norbornene-Endo-2,3-dicarboxylic acid (ndaH2): X-ray crystal structure of [Mn(η1η1-nda)(phen)2]·EtOH·H2O (phen = 1,10-phenantholine). Polyhedron, 14 (15-16). pp. 2247-2253. ISSN 0277-5387
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Abstract
Manganese(II) chloride reacts with the sodium salt of cis-5-norbornene-endo- 2,3-dicarboxylic acid (ndaH2) in aqueous media to give the manganese(II) complex [Mn (nda)H20] (1), Complex 1 reacts with I, 10-phenanthroline (phen) to give the mononuclear manganese(II) adduct [Mn(171171-nda)(phenh] · EtOH · H20 (2), The X-ray crystal structure of 2 shows the manganese atom at the centre of a distorted N402 octahedron comprising four nitrogen atoms from two chelating phen ligands, and two oxygen atoms, one from each of the two carboxylate functions of the nda2 - ligand. Spectroscopic and magnetic data for 1 and 2 are reported, together with their catalytic activity towards the disproportionation ofH202•
| Item Type: | Article |
|---|---|
| Additional Information: | Cite as: Michael Devereux, Martin Curran, Malachy McCann, Michael T. Casey, Vickie McKee, Vickie McKee, Synthesis and catalase activity of manganese(II) complexes of cis-5-norbornene-Endo-2,3-dicarboxylic acid (ndaH2): X-ray crystal structure of [Mn(η1η1-nda)(phen)2]·EtOH·H2O (phen = 1,10-phenantholine), Polyhedron, Volume 14, Issues 15–16, 1995, Pages 2247-2253, ISSN 0277-5387, https://doi.org/10.1016/0277-5387(94)00492-W |
| Keywords: | Synthesis; catalase activity; manganese(II) complexes; cis-5-norbornene-Endo-2,3-dicarboxylic acid (ndaH2); X-ray crystal structure; [Mn(η1η1-nda)(phen)2]·EtOH·H2O (phen = 1,10-phenantholine); |
| Academic Unit: | Faculty of Science and Engineering > Chemistry |
| Item ID: | 14694 |
| Identification Number: | 10.1016/0277-5387(94)00492-W |
| Depositing User: | Dr. Malachy McCann |
| Date Deposited: | 11 Aug 2021 14:32 |
| Journal or Publication Title: | Polyhedron |
| Publisher: | Elsevier |
| Refereed: | Yes |
| Related URLs: | |
| URI: | https://mu.eprints-hosting.org/id/eprint/14694 |
| Use Licence: | This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available here |
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