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Devereux, Michael, McCann, Malachy, Casey, Michael T., Curran, Martin, Ferguson, George, Cardin, Christine, Convery, Moira and Quillet, Valerie (1995) Binuclear and Polymeric Manganese (II) Salicylate Complexes: Synthesis, Crystal Structure and Catalytic Activity of [Mn2(Hsal)4(H2O)4] and [{Mn2(sal)2(Hsal)(H2O)-(H3O)(py)4-2py}2n] (H2sal=salicylic acid, py=pyridine). Journal of the Chemical Society, Dalton Transactions, 1. pp. 771-776.
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Abstract
The two air-stable manganese(II) salicylate complexes [Mn2(Hsal)4(H2O)4] 1 and poymeric [Mn2(sal)2(Hsal)(H2O)(H3O)(py)4-2py}.,,] 2 (H2sal=salicylic acid and py=pyridine) have been synthesised easily, and their crystal structures determined. Both contain unsymmetrically bridging salicylate ligands. In the presence of added pyridine 1 and 2 vigorously catalyse the dis-proportionation of H2O2.
| Item Type: | Article |
|---|---|
| Keywords: | Binuclear; Polymeric; Manganese (II); Salicylate Complexes; Synthesis; Crystal Structure; Catalytic; Activity; of [Mn2(Hsal)4(H2O)4]; [{Mn2(sal)2(Hsal)(H2O)-(H3O)(py)4-2py}2n]; (H2sal=salicylic acid, py=pyridine); |
| Academic Unit: | Faculty of Science and Engineering > Chemistry |
| Item ID: | 14513 |
| Depositing User: | Dr. Malachy McCann |
| Date Deposited: | 04 Jun 2021 14:57 |
| Journal or Publication Title: | Journal of the Chemical Society, Dalton Transactions |
| Refereed: | Yes |
| Related URLs: | |
| URI: | https://mu.eprints-hosting.org/id/eprint/14513 |
| Use Licence: | This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available here |
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