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Sung, Simon, Joachim, Timothy, Krämer, Tobias and Young, Rowan D. (2017) Protonolysis of an α-Hydroxyl Ligand for the Generation of a PCcarbeneP Pincer Complex and Subsequent Reactivity Studies. Organometallics, 36 (16). pp. 3117-3124. ISSN 0276-7333
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Abstract
A rhodium α-hydroxylalkyl complex (1) reacts rapidly with Brookhart’s acid, [H(OEt2)2][B(3,5-(CF3)2-C6H3)4], to generate a cationic PCcarbeneP complex (2). Complex 2 can also be accessed from salt metathesis of an α-hydroxyalkyl hydrochlorido rhodium(III) complex (4) with Na[B(3,5-(CF3)2-C6H3)4]. The reactivity of compound 2 is explored through a series of reactions with various nucleophilic and electrophilic reagents.
| Item Type: | Article |
|---|---|
| Keywords: | Carbene; Palladium; Rhodium; Iridium; Nickel; Molecular Structure; Metallacyclic Manganese; Stabilization; Chemistry, Organic; Ruthenium; C-H Activation; Chemistry, inorganic & nuclear; |
| Academic Unit: | Faculty of Science and Engineering > Chemistry |
| Item ID: | 11594 |
| Identification Number: | 10.1021/acs.organomet.7b00461 |
| Depositing User: | Tobias Kraemer |
| Date Deposited: | 04 Nov 2019 15:02 |
| Journal or Publication Title: | Organometallics |
| Publisher: | American Chemical Society |
| Refereed: | Yes |
| Related URLs: | |
| URI: | https://mu.eprints-hosting.org/id/eprint/11594 |
| Use Licence: | This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available here |
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