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McKay, Alasdair I., Krämer, Tobias, Rees, Nichollas H., Thompson, Amber L., Christensen, Kirsten E., Macgregor, Stuart A. and Weller, Andrew S. (2017) Formation of a σ-alkane complex and a molecular rearrangement in the solid-State: [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H12)][BArF 4]. Organometallics, 36 (1). pp. 22-25. ISSN 0276-7333
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Abstract
Addition of H2 to the precursor [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H8)][BArF4] gives the σ-alkane complex [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H12)][BArF4] by a single-crystal to single-crystal reaction, as characterized by X-ray crystallography, SSNMR spectroscopy, and periodic DFT. An unexpected rearrangement of the {Rh(L2)}+ fragment is revealed.
| Item Type: | Article |
|---|---|
| Keywords: | Paraffins; Molecular rearrangement; Periodic DFT; Single crystal-to-single crystal reactions; Single crystals; |
| Academic Unit: | Faculty of Science and Engineering > Chemistry |
| Item ID: | 11592 |
| Identification Number: | 10.1021/acs.organomet.6b00645 |
| Depositing User: | Tobias Kraemer |
| Date Deposited: | 04 Nov 2019 14:42 |
| Journal or Publication Title: | Organometallics |
| Publisher: | American Chemical Society |
| Refereed: | Yes |
| Related URLs: | |
| URI: | https://mu.eprints-hosting.org/id/eprint/11592 |
| Use Licence: | This item is available under a Creative Commons Attribution Non Commercial Share Alike Licence (CC BY-NC-SA). Details of this licence are available here |
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